The Bent Water Molecule – Why Is It Bent?

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bent water molecule
Liquid Water (Left) – Ice (Right)

The water molecule, H₂O, consists of two hydrogen atoms and one oxygen atom. A naïve attempt at writing its structure out in full is H‒O‒H. What’s naïve about this? This drawing is linear—a straight line. It is naïve because the water molecule is a bent water molecule… bent at about 104.5°.

It is a good thing for us that this is so, since this imparts a degree of polarity to the water molecule. Polarity, in turn, gives rise to hydrogen bonding. The hydrogen bonding of molecules assures water’s liquidity.

In addition hydrogen bonding influences water’s crystallization, so that ice is lighter than very cold water. Ice thus floats, forming an insulating blanket atop lakes and other bodies of water. This prevents them from freezing solid, killing all life within those bodies.

But a Question Arises

All well and good. But the inescapable question arises, “Why is it a bent water molecule and not straight?” What physical and/or chemical principles cause what would seem should be a straight molecule to bend? The answer lies with oxygen’s unbonded electron pairs. What is an unbonded pair?

Unbonded Electron Pairs

The oxygen atom center or nucleus ordinarily contains eight protons plus eight neutrons. A proton has a charge of +1 and a neutron of 0. To balance this electrical charge, the oxygen atom also possesses eight negative electrons in orbitals surrounding the nucleus.

Quantum enthusiasts will label the electronic structure: 1s² 2s² 2p⁴. Shell one contains only an “s” subshell, so it is completely filled. Shell two is not completely filled. The “p” subshell can hold 6 electrons, not just 4. The 2s + 4p electrons are called valence electrons. Oxygen has 6 valence electrons.

Bent Water Molecule
Each hydrogen atom contributes just one electron, to complete the octet, 2s² 2p⁶. The other 4 valence electrons do not bond to hydrogen. They are unbonded. Quantum mechanics dictates they associate in pairs.

The Bent Water Molecule

In view of the above, it becomes apparent the structure of water is much more accurately represented as an oxygen atom attached to two hydrogen atoms and two electron pairs. Notice the essentially tetrahedral layout in the image.

Note: You might also enjoy The Dipole Molecule Water – Mickey the Dipole


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